Key Mechanistic Features of Enantioselective C-H Bond Activation Reactions Catalyzed by [N-Protected Amino Acid-Pd(II)] ...
Published in Journal of the American Chemical Society
Published in Journal of the American Chemical Society
Published in Journal of the American Chemical Society
Published in Accounts of Chemical Research
Published in Journal of the American Chemical Society
Published in Organometallics
Published in Organometallics
Published in Accounts of Chemical Research
Published in Organic process research & development
Reaction methods for selective C-H amination are finding ever-increasing utility for the preparation of nitrogen-derived fine chemicals. This brief account highlights the remarkable versatility of dirhodium-based catalysts for promoting oxidation of aliphatic C-H centers in both intra- and intermolecular reaction processes.
Published in Quarterly Reviews Chemical Society
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Published in Journal of the American Chemical Society
The mixed-valent paddlewheel complex tetrakis(2-oxypyridinato) diruthenium (II,III) chloride, [Ru(2)(hp)(4)Cl], catalyzes intramolecular allylic C-H amination with bis(homoallylic) sulfamate esters. These results stand in marked contrast to reactions performed with dirhodium catalysts, which favor aziridine products. The following discussion consti...